Rust removal from chains?

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Iron out works pretty good. Just mix it with water and let it soak for 24 hours. Or just use an old bar and run the chain through some wood and the wood will buff the rust right off.
 
This includes the acetic acid in vinegar. Vinegar will not stop with removing rust, it will remove iron as well, further reducing the base metal.
Part of it is to use a weak solution, limit exposure, and rinse well afterwards. Some acids (hydrochloric, sulfuric, nitric) are especially damaging.

Philbert
 
If you use vinegar or acid or anything with a low pH, you should probably degrease the chains really well first with something that has a high pH, like lye or ammonia or oven cleaner or Simple Green, because acids can't cut through grease (think: oil and vinegar), but bases (ammonia, lye, etc.) can – which is how oven cleaner (lye) cuts through grease in your oven, or ammonia cuts through wax/grease on your floor.

After you degrease with lye/ammonia/oven cleaner, then rinse the chains well with water, then hit them with vinegar/acid, then rinse again, then oil.

If you try to use acid without degreasing first, the acid will never touch anything that has a film of oil (including petroleum solvents) over it.
Bases remove grease, oil, petroleum, etc.
Acids remove rust ... and eventually, metal.

After removing rust with acid/vinegar, and rinsing, it's probably not a bad idea to hit the chain once more with a weak solution of ammonia to neutralize any residual acid (in rivets and crevices, etc.) before rinsing one final time, then drying and oiling. (Better to leave a residual base than a residual acid.)

In a nutshell: Degrease with a base. Then de-rust with an acid. Then neutralize with a base. Then rinse/dry/oil.
 
If you try to use acid without degreasing first, the acid will never touch anything that has a film of oil over it.
Spoke to a chemist about degreasing (in the Challenge Chain thread). He broke them down into 3, general families:
- caustics (e.g. lye, sodium hydroxide, etc.);
- citrus based (limonline, orange, etc.);
- petroleum solvents (e.g. in parts washer).

Each has its advantages and disadvantages. Use caution with each for skin / eye contact, flammability, fumes, etc.

Philbert
 
Spoke to a chemist about degreasing (in the Challenge Chain thread). He broke them down into 3, general families:
- caustics (e.g. lye, sodium hydroxide, etc.);
- citrus based (limonline, orange, etc.);
- petroleum solvents (e.g. in parts washer).

Each has its advantages and disadvantages. Use caution with each for skin / eye contact, flammability, fumes, etc.

Only the first two will make it possilble to rinse off oil/grease with water and then get off the rust with acid. And emulsifiers/saponifiers like jojoba oil (Gojo) or limonene ('orange oil') are iffy. As for petroleum solvents, if a film remains after degreasing, the acid generally won't cut through it. This is why gunsmiths use lye to degrease guns before re-bluing them.
 
I have a couple of old metal hubcaps that happen to fit nicely on a couple of old coffee pot hot plates (one of them is a Melitta, for example).

I have soaked chains in various warmed solvents and oils in these hubcaps, periodically taking them out to work the kinks out, draining them, brushing them, wiping them, etc..

It's a crap shoot. A few chains recover, many don't. They almost never come back completely.

it's most unfortunate that the OP lost a bunch of good equipment! Hopefully some of those chains can be salvaged.
 
Kroil just let them soak in it. When done soak them in bar oil, then run them.
 
Its just a loop of chain. Disposable. If the bar oil and heat from the wood don’t free it up, just chuck it out.
Some of this is just experimentation for curiosity; gotta rule out the 'what does not work' to find the 'what works' stuff. Some of what we learn on 'scrap chains' can be useful on more valuable stuff later on. Some older chains are no longer available, so it can be helpful to collectors.

A lot of this I have down to a 'system' now, where it takes me little time to decide what is worth saving and what is not. Does not take a lot of time once you have it worked out.

Best 'system' is to keep the chains from getting rusted in the first place!

Philbert
 
I save older worn chains oiled up in zip loc bags. I cut pallets to burn when I get broken ones. I use the wornout chains and bars.
 
:blob2:Just don't use that Howes winter diesel conditioner/antigel/dewaterer in extreme cold weather, as it fails miserably.
just a little aside..


back to filthy rotten chains smokin' in the acid bath...

:blob2::blob2::blob2:
 
Some of this is just experimentation for curiosity; gotta rule out the 'what does not work' to find the 'what works' stuff. Some of what we learn on 'scrap chains' can be useful on more valuable stuff later on. Some older chains are no longer available, so it can be helpful to collectors.

A lot of this I have down to a 'system' now, where it takes me little time to decide what is worth saving and what is not. Does not take a lot of time once you have it worked out.

Best 'system' is to keep the chains from getting rusted in the first place!

Philbert

Trust me. I can tell you in less than a second if a chain is worth running. Aint my first day at the rodeo and time is money.

People actually collect saw chain?? Sweet Jesus. Now I have heard just about everything. Old tools and old fools. Cant separate them.
 

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