The water based degreaser that I use ('SuperClean') contains sodium hydroxide (a.k.a. 'lye') and it works much better than other 'purple cleaners'. In my 'Challenge Chain' thread I also tried pure lye (sold for drain cleaning in hardware stores, or in 'food grade' purity on Amazon, etc.), and even wood ashes (pioneer method of making lye) to clean chains.Somewhere I heard about cleaning off the pitch with oven cleaner/lye, and it seems to work well
Sodium hydroxide does react with aluminum, so use a glass or plastic container for cleaning.
Philbert