...now my metal boiler pipe is the highest point on the roof...
Are we talking a wood boiler, or some other "in-building" boiler??
Lightning protection for in-building boilers and boiler stacks may be... well... tricky when it comes to lightning protection. Typically a boiler has some sort of sensitive electronics critical to operation... and a malfunctioning boiler can be darn dangerous, not only to you and your home, but the whole neighborhood. I won't even pretend that I know what is correct, but I have seen lightning protection on boilers and boiler stacks. I suspect that basic grounding wouldn't be enough (and may even be dangerous??), more likely a protection system employing surge/lightning suppressors/arresters would be appropriate... but, again,
I do not know. If you did decide to do something I would, in this case, definitely recommend you consult an electrician, maybe even the boiler/boiler electronics manufacturer, and possibly check local code and your insurance company. You may even find out that surge/lightning protection was installed with the boiler, or included in its design and installation.
You are correct in that a lower resistance to ground is required for protection of sensitive electronics. ... My setup is just for the protection of the structure in the event of a strike since I have a 14ft metal pole sticking up on the top of my roof.
Even so, you did lower resistance to earth ground with the additional ground point (rod). You can look at each ground point as a separate resistor (as long as they are enough distance apart), and whenever you have two or more resistors in parallel (bonding them together makes them parallel) total resistance will be something less than the value of the lowest single resistor. The formula for that looks like this...
r = 1/[(1/r1)+(1/r2)]
So, for example, if your service ground was 20 ohms, and your additional ground rod has, say 40 ohms resistance...
- r = 1/[(1/20)+(1/40)]
- r = 1/(.05+.025)
- r = 1/.075
- r = 13.33 ohms of earth ground resistance
Of course we have no idea what the resistance is at your additional ground point, it may be 500 ohms (likely much, much lower), making the total 19.23 ohms... which would hardly be worth the effort.