Octane is not the flash point. Have you ever watched or done an octane test? The octane number is the % of pure octane that has equal knock resistance to the fuel In question.
To determine the octane of a fuel, you run your test fuel in a test motor, research or motor style depending on which number you are testing. adjust to find where it knocks, then change the fuel from the test fuel to a mix of octane and another hydrocarbon. When the mix of octane starts to knock, that % of octane is the octane number.
flash point is the temperature that a fuel will support burning. Low flash point hydrocarbons are dangerous because they will burn at room temperatures. High flash points mean it won’t burn unless heated. Flashpoint is useful to compare oils and how well they burn, thus leaving spooge.